Sodium Formate for Leather
CAS NO.: 141-53-7
Molecular Formula: HCOONa
Molecular Weight: 68.01 g/mol
Character: White crystalline powder or fine granules, readily soluble in water and suitable for controlled leather-processing formulations.
Usage: Used during tanning, pickling, neutralization, dyeing, and finishing. It helps control pH, improve tanning-agent distribution, reduce localized acidity, and enhance the softness, fullness, and color uniformity of finished leather.
Package: 25 kg moisture-resistant bag with an inner polyethylene liner.
Storage: Keep tightly sealed in a cool, dry, and ventilated place. Avoid moisture and incompatible chemicals.
- Product Description
Premium Sodium Formate for Leather Tanning – High-Purity Masking Agent for Strong Chrome Fixation
Shanxi Zhaoyi Chemical Co., Ltd. was founded in 1988, focusing on the R&D and production of reliable leather processing chemicals. Our 27,000 m² standardized production base features a stable annual output of 150,000 tons, fully guaranteeing large-scale and continuous supply for global tanneries. Our professional-grade Sodium Formate for Leather is available in 95% and 98% high purity grades, with ultra-low iron content controlled below 0.005%. Tailored for chrome tanning processes, it effectively avoids acid shock during pickling and tanning, stabilizes the system pH at 3.5-4.5, and significantly boosts chrome exhaustion rate beyond industry average standards. Supported by ISO, KOSHER and HALAL certifications, our products are widely exported to Europe, America, Asia and other regions, delivering uniform penetration and stable fixation for thick bovine hides and delicate special leathers.

Key Features & Benefits
Traditional tanning has many common pain points. Professional this product fixes them. It relies on clear buffering and masking mechanisms. Product quality becomes steadier, and defective rates fall:
Formate ions in the product can replace sulfate ions inside chrome complexes. That keeps collagen and chromium ions bound in a steady state. Early surface fixation is blocked. In thick hides, raw centers that chrome never reaches are no longer a problem. Chrome spreads evenly across leather of different thickness. Grain looseness goes away. Leather flatness gets better.
The powder has high water solubility: 97g/100ml at 20°C. In tanning floats it dissolves fast. No caking. No precipitation. Automated tanning equipment can dose it with accuracy and steady results. That fits modern large-scale assembly line production.
Chloride content stays tightly controlled and low. Salt spue then has a hard time forming on the surface of finished leather. For high-end automotive upholstery leather and aniline leather, this is the auxiliary material to reach for. Surface appearance defects that drag down product grading do not show up at all.
Iron content is extremely low. The standard grade sits below 50ppm, and the premium grade drops to 5ppm. Black spot staining on light-colored and pastel leathers gets stopped at the source. Rejection rates fall a long way, so tanneries come out ahead on cost.

Technical Specifications
Parameter | Standard Grade | Premium Grade |
Purity (HCOONa) | ≥95.0% | ≥98.0% |
Iron (Fe) Content | <0.005% (50ppm) | <0.0005% (5ppm) |
Moisture Content | <3.0% | <2.0% |
Insolubles | <0.1% | <0.05% |
Chloride (Cl⁻) | <0.5% | <0.2% |
Specific Gravity | 1.92 | 1.92 |
Water Solubility (20°C) | 97g/100ml | 97g/100ml |
pH (10% solution) | 7.0-8.5 | 7.0-8.5 |

How It Works
Sodium Formate for Leather has stable chemical properties. It improves the whole tanning run, from pickling all the way to neutralization, and the result is refined and reliable:
At the pickling stage it evens out the osmotic pressure on both sides of the leather fiber matrix. Acid swelling drops as a result. Fine grain structures, sheepskin included, stay safe from harm. The raw material keeps its natural texture.
Formate ions join with trivalent chromium ions during chrome tanning and build stable complexes. That lets plants raise the basification pH to 4.0-4.5 in a steady way. Chromium does not come out of solution too early. The tanning bath stays stable.
Masking works well here. The tanning liquor reaches deep into the leather fibers before fixation. Temperature swings in the drums no longer cause uneven tanning or color differences. Leather quality stays consistent all through the batch.
During the later neutralization stage, the internal pH of the leather goes up slowly and in a steady way. Fatliquors and dyes can then spread evenly through the whole cross-section of the leather. They no longer fix only at the surface. Color comes out more even, and the finished leather feels fuller and softer.
Applications
This product covers mainstream application scenarios of modern leather tanning, adapting to different leather materials and high-end processing requirements:
Chrome Tanning of Heavy Bovine Hides: This is a core masking agent for shoe upper leather and automotive leather. In thick belly and shoulder parts of cattle hides, it helps the chrome go in evenly. The old problem of leather that is hard on the inside and different on the outside goes away.
High-End Aniline Leather Production: Here it works as a mild neutralizing agent in the retanning step. Aniline dyes stay away from too much surface fixation. The full-grain leather keeps its natural color depth and clear, see-through look.
Exotic Leather Processing: Pickling bath conditions stay steady for python, crocodile, ostrich and other special leathers. Under acidic tanning conditions, delicate fiber tissues and natural grain get protection from damage.
Wet-Blue Chrome Exhaustion: The chrome utilization rate climbs by 15-20%. Less residual chromium ends up in wastewater. Tanneries are better able to meet environmental standards for COD and heavy metal emissions.
Vegetable Retanning Combinations: System pH gets adjusted and balanced before vegetable tanning. This stops over-tanning and leather hardening. The finished leather still has excellent fullness and a soft hand feel.
Sodium Formate for Leather vs Other Products
Feature | Sodium Formate | Sodium Bicarbonate | Ammonium Sulfate | Magnesium Oxide |
Function | Masking Agent | Basifying Agent | Pickling Salt | Neutralizer |
pH Control | Gradual, stable | Rapid, aggressive | Acidic | Alkaline spike |
Chrome Exhaustion | 85-92% | 70-75% | N/A | 75-80% |
Grain Tightness | Excellent | Poor (swelling risk) | Moderate | Variable |
Iron Content Impact | Minimal (<5ppm) | N/A | High (staining risk) | Moderate |
Cost Efficiency | Moderate | Low | Low | Moderate |
Certifications & Compliance
Our production system strictly complies with HG/T 2-3000 industry quality standards for formate salts. Each batch of products undergoes rigorous testing including redox titration and atomic absorption spectroscopy to precisely control iron content and impurity indicators.
We have obtained ISO 9001:2015 quality management system certification, realizing standardized control from raw material procurement, synthetic production to finished product packaging. A complete batch traceability system is established to track every product batch.
Equipped with KOSHER and HALAL certifications, our products support leather manufacturers to access compliant markets in specific regions. Meanwhile, our testing laboratory holds CNAS accreditation, and official third-party inspection reports can be provided to meet customers’ import and export customs clearance requirements.

Packaging Options
We provide diversified professional packaging solutions tailored to the storage and transportation characteristics of leather-grade sodium formate:
Standard Packaging: product goes into 25kg woven polypropylene bags. Each bag is moisture-proof and has a PE liner inside. That liner blocks moisture from the air. So the product does not spoil while it sits in storage or travels.
High-Humidity Resistant Packaging: tropical areas and other damp places (relative humidity above 80%) get laminated bags with stronger vapor barrier layers. Product stability stays fully protected there.
Bulk Packaging: 1000kg jumbo bags, anti-static treated. Big tanneries that run automated pneumatic conveying systems can use them. Machines handle the loading and unloading with ease. Bulk transport gets easier too.
We also support customized multilingual labels (English, Spanish, Portuguese, Arabic) and private packaging services to meet personalized distribution needs of global partners.

Manufacturing Process
The direct carbonylation synthesis technology we use is mature. High-purity carbon monoxide and sodium hydroxide serve as the raw materials. They react at constant pressure and temperature. Tight control covers every step. That limits impurity formation and keeps product purity high.
After synthesis, the crude material goes through several crystallization rounds. These rounds remove leftover salts and organic impurities. Next comes centrifugal separation, then fluidized bed hot air drying. Moisture content stays below 2%.
Ribbon mixers built for the job blend in 0.1-0.3% of a uniform anti-caking agent. This formula does not affect tanning performance. It also stops the product from clumping during long-term storage.
The automated line flushes every pack with nitrogen. That pushes shelf life up to 24 months. Before palletizing, each finished item passes metal detection and a weight check, one at a time. Delivery only starts after that, so what leaves the plant meets the Sodium Formate for Leather quality standard.
Why Choose Us
With 36 years of professional experience in formate and acetate chemical production, we have in-depth insight into the actual production pain points and quality standards of the tanning industry. Our professional technical team provides targeted application guidance according to customers’ different leather types and production processes.
The stable annual production capacity of 150,000 tons and sufficient raw material inventory completely avoid supply shortages and quality fluctuations in peak tanning seasons, ensuring customers’ continuous and stable production.
We have built a mature global distribution network covering more than 40 countries, with regional warehouses in Europe and Southeast Asia. The average container shipping cycle is controlled at 15-20 days, with efficient and stable delivery.
We own the whole production chain, from the raw material up. Core raw materials come out of our own lines. No middleman markup gets added along the way. Buyers pay a factory direct price, and that keeps their costs down.
Technical questions and fault reports land with our after-sales team, and an answer goes back within 4 hours. pH regulation, chrome fixation, other tanning troubles: help shows up while the problem is still fresh. Customers are not left waiting.

FAQ
Q: What causes sodium formate caking during storage?
A: A1: Sodium formate is inherently hygroscopic. Caking easily occurs in high temperature and high humidity environments. We add professional anti-caking ingredients, and it is recommended to store the product below 30°C with relative humidity under 60% for optimal storage effect.
Q: Can sodium bicarbonate replace sodium formate in tanning?
A: A2: Replacement is not recommended. Sodium bicarbonate causes rapid surface chrome fixation and case hardening, resulting in poor internal penetration. Sodium formate features distinct masking performance to realize deep and uniform tanning.
Q: How does sodium formate improve chrome exhaustion rate?
A: A3: It stabilizes chrome ions under high pH conditions to avoid premature precipitation. It reduces residual chrome concentration in tanning liquor to 200-300ppm, far lower than the 800-1000ppm of traditional processes, greatly improving chrome utilization.
Q: How to choose between standard grade and premium grade?
A: A4: The 95% standard grade is cost-effective for dark leather production. The 98% premium grade with ultra-low iron content is suitable for white automotive leather and exotic leather to completely avoid iron staining defects.
Q: What positive effects does it have on leather grain?
A: A5: It relieves acid swelling of leather fibers and achieves gradual and uniform chrome fixation. The leather fiber structure is tighter and more stable, with smoother and finer grain surface and better overall appearance.

Request a Quote
Feel free to contact our professional technical sales team at sxzy@sxzhaoyi.com to get customized quotations, and exclusive Sodium Formate for Leather tanning process solutions tailored to your production lines.


